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Ricerca Persone

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SCARSO Alessandro

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Attività e competenze di ricerca

Settore Scientifico Disciplinare (SSD) di afferenza
Settore Scientifico Disciplinare (SSD) affine
Aree e linee di ricerca

Competenze di ricerca

catalisi omogenea anche asimmetrica

Description
  • homogeneous catalysis, asymmetric catalysis
Parole Chiave
  • Homogeneous catalysis, Carbon chemistry, Organometallic chemistry
Codice ATECO
  • [21] - fabbricazione di prodotti farmaceutici di base e di preparati farmaceutici

green chemistry

Description
  • green chemistry
Parole Chiave
  • Homogeneous catalysis, Organic chemistry, Reaction mechanisms ands dynamics
Codice ATECO
  • [21] - fabbricazione di prodotti farmaceutici di base e di preparati farmaceutici

sintesi di bisfosfonati quali farmaci epr il contrasto dell

Description
  • bisphosphonate synthesis as anti-osteoporosis drugs
Parole Chiave
  • Homogeneous catalysis, Organic chemistry
Codice ATECO
  • [21] - fabbricazione di prodotti farmaceutici di base e di preparati farmaceutici

catalisi micellare in acqua

Description
  • micellar catalysis in water
Parole Chiave
  • Homogeneous catalysis, Organic chemistry
Codice ATECO
  • [21] - fabbricazione di prodotti farmaceutici di base e di preparati farmaceutici

Ricerche sviluppate e in corso

Catalisi supramolecolare mediante interazione tra hosts auto-assemblati e complessi organometallici

SSD
  • CHIM/04

Uso di acqua come mezzo di reazione in chimica organica industriale

SSD
  • CHIM/04

Catalizzatori omogenei fotomodulabili

SSD
Altri membri del gruppo di ricerca

Sintesi di molecole bioattive a base di bisfosfonati per la terapia e la diagnosi di malattie osteolitiche

SSD
Altri membri del gruppo di ricerca

Catalisi supramolecolare

SSD
Altri membri del gruppo di ricerca

Reazioni di ossidazione selettiva con catalizzatori a base di metalli nobili

SSD
  • CHIM/04
Altri membri del gruppo di ricerca

Uso dell'acqua come solvente per reazioni catalitiche in chimica organica industriale

SSD
  • CHIM/04
Altri membri del gruppo di ricerca

Reazioni di ossidazione selettiva con H2O2 mediate da catalizzatori di metalli nobili

SSD
  • CHIM/04
Altri membri del gruppo di ricerca

Sintesi di nuovi bisfosfonati chirali e non quali potenziali farmaci per il contrasto dell'osteoporosi

SSD
  • CHIM/06

Finanziamenti

Sintesi di bisfosfonati mediante reazioni catalitiche con complessi solubili di metalli di transizione.

Ente finanziatore
  • MIUR
Tipologia
  • PRIN
Ruolo nel progetto
  • LD
Data inizio
  • Anno: 2010 Durata mesi: 24
Altri membri del gruppo di ricerca

Aree geografiche in cui si applica prevalentemente l'esperienza di ricerca

Internazionale: America Settentrionale,Europa, Estremo Oriente, Medio Oriente

Lingue conosciute

  • inglese (scritto: avanzato, parlato: avanzato)

Partecipazione a comitati editoriali di riviste/collane scientifiche

Referee delle seguenti riviste interazioniali per review: 1) Angewandte Chemie Internation Edition English, 2) Journal of the American Chemical Society 3) Accounts of Chemical Research 4) Chemical Communication 5) Advanced Synthesis and Catalysis 6) Israel Journal of Chemistry 7) Inorganica Chimica ACTA 8) Central European Journal of Chemistry 9) Polyhedron 10) Chemical Papers Reviewer approvato ed operativo per la valutazione nazionale VQR 2004-2010

Partecipazione come referees di progetti di ricerca nazionali ed internazionali

National and International Collaborations • Prof. R.A. Michelin e Prof. M. Basato, Universitá di Padova, development of new Pt(II) and Pd(II) complexes in oxidation reactions. • Prof. O. Bortolini Università di Ferrara and Dr. D. Granchi, Istituto Ortopedico Rizzoli, Bologna, synthesis and evaluation of the biological activity of new bisphosphonates as potential drug candidates for bone resorption diseases like osteoporosis. • DSM research, Dr. L Lefort, The Netherlands, employment of chiral phosphoramide ligands in asymmetric oxidation reactions. • Prof. Lipshutz, University California Santa Barbara (CA) USA, employment of PTS neutral surfactant in micellar catalysis. • Prof. D. Wass, School of Chemistry, University of Bristol, employment of PNP ligands for homogeneous catalysis in micellar media, development of photocromic ligands for catalysis • Prof. J. Reek, University of Amsterdam, development of encapsulated homogeneous metal catalysts for selective catalysis

Pubblicazioni per Anno

2013

  • Stefano Tartaggia, Ottorino De Lucchi, Andrea Gambaro, Roberta Zangrando,Fabrizio Fabris,* Alessandro Scarso* Chiral M3L2 Self-Assembled Capsules through Metal Coordination of Enantiopure Ligating Benzocyclotrimers: NMR Spectroscopic and ESI Mass Spectrometric Investigation, in CHEMISTRY-A EUROPEAN JOURNAL, vol. 19, pp. 5701-5714 (ISSN 0947-6539) Link DOI (Articolo su rivista)
  • Giorgio La Sorella; MAttia Bazan; Alessandro Scarso; Giorgio Strukul Competitive micellar induced substrate selectivity in the Pd mediatedheck coupling between iodoaryl substrates and linear acrylic esters inwater, in JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL, vol. 379, pp. 192-196 (ISSN 1381-1169) Link DOI (Articolo su rivista)
  • G. Bianchini, G. La Sorella, N. Canever, A. Scarso, G. Strukul Efficient isonitrile hydration through encapsulation within a hexameric self-assembled capsule and selective inhibition by a photo-controllable competitive guest, in CHEMICAL COMMUNICATIONS, vol. 49, pp. 5322-5324 (ISSN 1359-7345) Link DOI (Articolo su rivista)
  • Donatella Granchi, Alessandro Scarso, Giulio Bianchini, Andrea Chiminazzo, Alberto Minto, Paolo Sgarbossa, Rino A. Michelin, Gemma Di Pompo, Sofia Avnet, Giorgio Strukul Low toxicity and unprecedented anti-osteoclast activity of a simple sulfur-containing gem-bisphosphonate: A comparative study, in EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, vol. 65, pp. 448-455 (ISSN 0223-5234) Link DOI (Articolo su rivista)
  • Cavarzan A., Reek J.N.H., Trentin F., Scarso A., Strukul G. Substrate selectivity in the alkyne hydration mediated by NHC-Au(i) controlled by encapsulation of the catalyst within a hydrogen bonded hexameric host, in CATALYSIS SCIENCE & TECHNOLOGY, vol. 3, pp. 2898-2901 (ISSN 2044-4761) Link DOI (Articolo su rivista)
  • Bianchini G., Scarso A., Chiminazzo A., Sperni L., Strukul G. Water Enhanced Synthesis of gem-Bisphosphonates via Rh(I) Mediated 1,4-Conjugate Addition of Aryl Boronic Acids to Vinilydenbisphosphonate Esters, in GREEN CHEMISTRY, vol. 15, pp. 656-662 (ISSN 1463-9262) Link DOI (Articolo su rivista)
  • Alessandro Scarso, Giorgio Strukul Catalytic Oxidation Processes, Comprehensive Inorganic Chemistry II, vol 6 Homogeneous Catalytic Applications, Oxford, Elsevier, vol. 6, pp. 177-221 (ISBN 9780080977744) (Articolo su libro)
  • G. Strukul, A. Scarso Environmentally Benign Oxidants, Liquid Phase Oxidation via Heterogeneous Catalysis, London, John Wiley & Sons, Ltd , pp. 1-20 (ISBN 9780470915523) (Articolo su libro)
  • A. Scarso, G. Strukul Transition-Metal-Catalyzed Asymmetric Sulfoxidation in Drug and Natural Product Synthesis, Stereoselective Synthesis of Drugs and Natural Products, Weinheim, WILEY-VCH, pp. 1473-1480 (ISBN 9781118032176) (Articolo su libro)
  • A. Scarso, G. Strukul Transition-Metal-Catalyzed Stereoselective Oxidations in Drug and Natural Product Synthesis, Stereoselective Synthesis of Drugs and Natural Products, Weinheim, WILEY-VCH, pp. 1043-1070 (ISBN 9781118032176) (Articolo su libro)
  • F. Fabris, C. Fabbro, G. Borsato, A. Scarso, O. De Lucchi Molecular Basket, Capsule, Cage and Clam from Enantiomerically Pure Benzocyclotrimers, Suprachem 2013 - XI Congresso Nazionale di Chimica Supramolecolare, Società Chimica Italiana, pp. OC9-OC9, Convegno: Suprachem 2013 - XI Congresso Nazionale di Chimica Supramolecolare, Padova, 24-27 settembre 2013 (Abstract in Atti di convegno)

2012

  • Paolo Sgarbossa, Alessandro Scarso, Giorgio Strukul, Rino A. Michelin Platinum(II) Complexes with Coordinated Electron-Withdrawing Fluoroalkyl and Fluoroaryl Ligands: Synthesis, Reactivity, and Catalytic Activity, in ORGANOMETALLICS, vol. 31, pp. 1257-1270 (ISSN 0276-7333) Link DOI (Articolo su rivista)
  • Francesco Trentin, Andrew M. Chapman, Alessandro Scarso, Paolo Sgarbossa, Rino A. Michelin, Giorgio Strukul, Duncan F. Wass Platinum(II) Diphosphinamine Complexes for the Efficient Hydration of Alkynes in Micellar Media, in ADVANCED SYNTHESIS & CATALYSIS, vol. 354, pp. 1095-1104 (ISSN 1615-4150) Link DOI (Articolo su rivista)
  • Giulio Bianchini, Alessandro Scarso, Giorgio La Sorella, Giorgio Strukul Switching the activity of a photoredox catalyst through reversible encapsulation and release, in CHEMICAL COMMUNICATIONS, vol. 48, pp. 12082-12084 (ISSN 1359-7345) Link DOI (Articolo su rivista)
  • SCARSO A.; BORSATO G. Self-Assembly of Organic Supramolecular Capsules, Supramolecular Chemistry: from Molecules to Nanomaterials,, Chichester, UK, J.W. Steed and P.A. Gale (eds)John Wiley & Sons Ltd, pp. 2085-2114 (ISBN 9780470746400) (Articolo su libro)
  • Giorgio Strukul, Alessandro Scarso ORGANOCATALYTIC ENANTIOSELECTIVE EPOXIDATION OF ARYL SUBSTITUTED VINYLIDENBISPHOSPHONATE ESTERS: ON THE WAY TO CHIRAL ANTI-OSTEOPOROSIS DRUGS, ADHOC 2012, Convegno: International Symposium on Activation of Dioxygen and Homogeneous Catalytic Oxidation 2012, Gerusalemme, Settembre 2012 (Abstract in Atti di convegno)

2011

  • Trentin Francesco, Scarso A., Strukul G. Micellar-driven substrate selectivity in Cr(salen)Cl catalytic Diels–Alder reaction in water, in TETRAHEDRON LETTERS, vol. 52, pp. 6978-6981 (ISSN 0040-4039) Link DOI (Articolo su rivista)
  • Cavarzan A., Scarso A., Sgarbossa P., Strukul G., Reek J.N.H. Supramolecular Control on Chemo- and Regioselectivity viaEncapsulation of (NHC)-Au Catalyst within a HexamericSelf-Assembled Host, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 133, pp. 2848-2851 (ISSN 0002-7863) Link DOI (Articolo su rivista)
  • A. Scarso, G. Borsato, J. Rebek Jr. Capsules and cavitands: synthetic catalysts of nanometric dimension, Selective nanocatalysts and nanoscience, Weinheim, Wiley-VCH, pp. 105-168 (ISBN 9783527322718) (Articolo su libro)
  • G. Bianchini, A. Scarso, G. Strukul A Photomodulable organometallic catalyst, SCI 2011, SCI, Convegno: XXIV Congresso Nazionale della Società Chimica Italiana (Articolo in Atti di convegno)
  • Tartaggia S, Fabris F., Scarso A, De Lucchi O Supramolecular Capsules Based on Metal Coordination or Hydrogen Bonding from Enantiopure Benzocyclotrimers, X Congresso Nazionale di Chimica Supramolecolare, pp. P58, Convegno: X Congresso Nazionale di Chimica Supramolecolare, Perugia (PG), 25-28 settembre (Articolo in Atti di convegno)
  • G. Strukul, A. Scarso Supramolecural Control on Product and Substrate Selectivity via Encapsulation within a Hydrogen Bonded Self-assembled Hexameric Capsule, SCI 2011, SCI, Convegno: XXIV Congresso Nazionale della Società Chimica Italiana (Articolo in Atti di convegno)

2010

  • CAVARZAN A; A. SCARSO; STRUKUL G Efficient Nitrile Hydration Mediated by Ru(II) Catalysts in Micellar Media, in GREEN CHEMISTRY, vol. 5, pp. 790-794 (ISSN 1463-9262) Link DOI (Articolo su rivista)
  • Gottardo M.; Scarso A.; Paganelli S.; Strukul G. Efficient Pt(II) Catalyzed Hydroformylation Reaction in Water: Unusual Product Distribution in Micellar Media, in ADVANCED SYNTHESIS & CATALYSIS, vol. 352, pp. 2251-2262 (ISSN 1615-4150) Link DOI (Articolo su rivista)
  • Alessandra Cavarzan, Alessandro Scarso, Paolo Sgarbossa, Rino A Michelin, Giorgio Strukul Green Catalytic Baeyer-Villiger Oxidation with Hydrogen Peroxide: In Water Reactions mediated by Pt(II) Catalysts, in CHEMCATCHEM, vol. 2, pp. 1296-1302 (ISSN 1867-3880) Link DOI (Articolo su rivista)
  • A. SCARSO; COLLADON M; SGARBOSSA P; SANTO C; MICHELIN R.A; STRUKUL G Highly Active and Selective Platinum(II)-Catalyzed Isomerization of Allylbenzenes: Efficient Access to (E)-Anethole and Other Fragrances via Unusual Agostic Intermediates, in ORGANOMETALLICS, vol. 29, pp. 1487-1497 (ISSN 0276-7333) (Articolo su rivista)
  • R.A. MICHELIN; P. SGARBOSSA; A. SCARSO; STRUKUL G. The Baeyer–Villiger oxidation of ketones: A paradigm for the role of soft Lewis acidity in homogeneous catalysis, in COORDINATION CHEMISTRY REVIEWS, vol. 254, pp. 646-660 (ISSN 0010-8545) Link DOI (Articolo su rivista)
  • Fabris F., Tartaggia S, Scarso A, De Lucchi O Benzocyclotrimers: Scaffolds for Supramolecular Chemistry, 8th Spanish-Italian Symposium on Organic Chemistry, pp. OC5, Convegno: 8th Spanish-Italian Symposium on Organic Chemistry, Padova, 03/07/2010-06/07/2010 (Articolo in Atti di convegno)
  • A. Cavarzan, A. Scarso, G. Strukul Efficient Nitrile Hydration Mediated by RuII Catalysts in Micellar Media, 3rd EUCHEMS Congress, EuCheMS, Convegno: 3rd EUCHEMS Congress, Nürnberg (D), 29/08-03/09/2010 (Articolo in Atti di convegno)
  • A. Scarso; G. Strukul Green Catalytic Asymmetric Baeyer-Villiger Oxidations in Water: Supramolecular Micellar Effects, XVII International Symposium on Homogeneous Catalysis, Polish Chemical Society, Convegno: XVII International Symposium on Homogeneous Catalysis, Poznan (PL), 04-09/07/2010 (Articolo in Atti di convegno)
  • G. Strukul, A. Scarso, M. Gottardo Hydroformylation in Micella Media, XVI Congresso Nazionale di Catalisi GIC 2010, GIC, Convegno: XVI Congresso Nazionale di Catalisi GIC 2010, Mondello (PA), 19-23/09/2010 (Articolo in Atti di convegno)
  • Tartaggia S.; Fabris F.; Scarso A.; De Lucchi O. Inclusion of Small Molecules in Benzocyclotrimer Based Hosts, 8th Spanish-Italian Symposium on Organic Chemistry, pp. P24, Convegno: 8th Spanish-Italian Symposium on Organic Chemistry, Padova, 03/07/2010-06/07/2010 (Articolo in Atti di convegno)
  • Fabris F., Tartaggia S., Scarso A., De Lucchi O. Nanocapsules, Nanocages and Metal-Organic Frameworks from Enantiomerically Pure Benzocyclotrimers, XXXIII Convegno Nazionale della Divisione di Chimica Organica Società Chimica Italiana - Atti del Convegno, pp. O5, Convegno: XXXIII Convegno Nazionale della Società Chimica Italiana Divisione di Chimica Organica, San Benedetto del Tronto (AP), 12-16 settembre (Articolo in Atti di convegno)

2009

  • G. BIANCHINI; A. CAVARZAN; A. SCARSO; STRUKUL G. Asymmetric Baeyer-Villiger Oxidation with Co(Salen) and H2O2 in Water: Striking Supramolecular Micelles Effect on Catalysis, in GREEN CHEMISTRY, vol. 11, pp. 1517-1520 (ISSN 1463-9262) Link DOI (Articolo su rivista)
  • A. CAVARZAN; G. BIANCHINI; P. SGARBOSSA; L. LEFORT; S. GLADIALI; A. SCARSO; STRUKUL G. Catalytic Asymmetric Baeyer-Villiger Oxidation in Water by Using PtII Catalysts and Hydrogen Peroxide: Supramolecular Control of Enantioselectivity, in CHEMISTRY-A EUROPEAN JOURNAL, vol. 15, pp. 7930-7939 (ISSN 0947-6539) Link DOI (Articolo su rivista)
  • SCARSO A. Catalytic Reactions in Micellar Media, in LA CHIMICA E L'INDUSTRIA, vol. 7, pp. 142-149 (ISSN 0009-4315) (Articolo su rivista)
  • TARTAGGIA S; SCARSO A; PADOVAN P; DE LUCCHI O.; FABRIS F Gases as Guests in Benzocyclotrimer Cage Hosts, in ORGANIC LETTERS, vol. 11, pp. 3926-3929 (ISSN 1523-7060) Link DOI (Articolo su rivista)
  • A. SCARSO; STRUKUL G. Compounds with One Saturated Carbon-Heteroatom Bond: Peroxides. Product Class 1: Alkyl and cycloalkyl Hydroperoxides in A. BERKESSEL, Science of Synthesis, STUTTGART, G. Thieme Verlag, vol. 38, pp. 9-71 (ISBN 9781588905291) (Articolo su libro)
  • A. SCARSO; STRUKUL G. Compounds with One Saturated Carbon-Heteroatom Bond: Peroxides. Product Class 4: Salts of alkyl Hydroperoxides in A. BERKESSEL, Science of Synthesis, STUTTGART, G. Thieme Verlag, vol. 38, pp. 143-178 (ISBN 9781588905291) (Articolo su libro)
  • SCARSO A., BORSATO G. Optically Active Supramolecules in AMABILINO D., Chirality at the Nanoscale, WEINHEIM, WILEY-VCH Verlag GmbH & Co. KGaA, pp. 29-65 (ISBN 9783527625345) (Articolo su libro)
  • TARTAGGIA S; FABRIS F; SCARSO A; DE LUCCHI O. Molecular Hosts from Benzocyclotrimers for Inclusion of Small Molecules, IX Congresso Nazionale di Chimica Supramolecolare, pp. P97, Convegno: IX Congresso Nazionale di Chimica Supramolecolare, Parma, 6-9 settembre 2009 (Articolo in Atti di convegno)

2008

  • SGARBOSSA P; FÁTIMA M; GUEDES DA SILVA C; SCARSO A.; MICHELIN R.A; POMBEIRO A.J.L Lewis Acidity of Platinum(II)-Based Baeyer–Villiger Catalysts: An Electrochemical Approach, in INORGANICA CHIMICA ACTA, vol. 361, pp. 3247-3253 (ISSN 0020-1693) (Articolo su rivista)
  • M. COLLADON; A. SCARSO; STRUKUL G. Mild Catalytic Oxidation of Secondary and Tertiary Amines to Nitrones and N-Oxides with H2O2 Mediated by Pt(II) Catalysts, in GREEN CHEMISTRY, vol. 10, pp. 793-798 (ISSN 1463-9262) (Articolo su rivista)
  • G. GREGGIO; P. SGARBOSSA; A. SCARSO; R. A. MICHELIN; STRUKUL G. Platinum(II) diphosphine complexes as catalysts for the Baeyer–Villiger oxidation of ketones: Is it possible to increase the concentration of the active species?, in INORGANICA CHIMICA ACTA, vol. 361, pp. 3230-3236 (ISSN 0020-1693) (Articolo su rivista)
  • STRUKUL G.; SCARSO A. Unprecedented selectivity in the H2O2 epoxidation of simple alkenes imparted by soft Pt(II) Lewis acid catalysts in S. T. OYAMA, Mechanisms in Homogeneous and Heterogeneous Catalytic Epoxidation, AMSTERDAM, Elsevier, pp. 103-117 (ISBN 9780444531889) (Articolo su libro)
  • COLLADON M; SCARSO A.; STRUKUL G Catalytic Reactions in Micellar Media: a Sustainable Methodology for Catalyst Recycling, International Congress SUPRACAT (SUPRAmoelcular CATalysis), Convegno: International Congress SUPRACAT (SUPRAmoelcular CATalysis), Barcelona (SPAIN), March 2-5 (Articolo in Atti di convegno)
  • STRUKUL G.; SCARSO A Soft Lewis Acids and Hydrogen Peroxide: a Viable Catalytic Approach to the Epoxidation of Simple Alkenes, 10th International Symposium on Activation of Dioxygen and Homogeneous Catalytic Oxidation (ADHOC), Convegno: 10th International Symposium on Activation of Dioxygen and Homogeneous Catalytic Oxidation (ADHOC), Venezia, July 20-25 (Articolo in Atti di convegno)

2007

  • SCARSO A.; PELLIZZARO L; DE LUCCHI O; LINDEN A; FABRIS F Gas Hosting in Enantiopure Self-Assembled Oximes, in ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, vol. 46, pp. 4972-4975 (ISSN 1433-7851) Link DOI (Articolo su rivista)
  • COLLADON M; SCARSO A; SGARBOSSA P; MICHELIN R.A; STRUKUL G. Regioselectivity and Diasteroselectivity in Pt(II)-Mediated "Green" Catalytic Epoxidation of Terminal Alkenes with Hydrogen Peroxide: Mechanistic Insight into a Peculiar Substrate Selectivity, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 129, pp. 7680-7689 (ISSN 0002-7863) Link DOI (Articolo su rivista)
  • P. SGARBOSSA; A. SCARSO; R. A. MICHELIN; STRUKUL G. Steric Effects in the Baeyer-Villiger Oxidation of Ketones Catalyzed by Platinum(II) Lewis Acid Complexes with Coordinated Electron-Donor Alkyl Diphosphines, in ORGANOMETALLICS, vol. 26, pp. 2714-2719 (ISSN 0276-7333) (Articolo su rivista)
  • P. SGARBOSSA; A. SCARSO; E. PIZZO; S. MAZZEGA SBOVATA; A. TASSAN; R.A. MICHELIN; STRUKUL G. Synthesis, characterization and Baeyer–Villiger oxidation of ketones by the bis-cationic platinum(II) complex [Pt(μ-OH)(Pom-Pom)]2[BF4]2 [Pom-Pom = (OMe)2PCH2CH2P(OMe)2], in JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL, vol. 261, pp. 202-206 (ISSN 1381-1169) (Articolo su rivista)
  • COLLADON M; SCARSO A.; STRUKUL G Towards a Greener Epoxidation Method: Use of Water-Surfactant Media and Catalyst Recycling in the Platinum-Catalyzed Asymmetric Epoxidation of Terminal Alkenes with Hydrogen Peroxide, in ADVANCED SYNTHESIS & CATALYSIS, vol. 349, pp. 797-801 (ISSN 1615-4150) (Articolo su rivista)
  • SCARSO A.; ZAUPA G; BODAR HOUILLON F; PRINS L.J; SCRIMIN P Tripodal, Cooperative, and Allosteric Transphosphorylation Metallocatalysts, in JOURNAL OF ORGANIC CHEMISTRY, vol. 72, pp. 376-385 (ISSN 0022-3263) (Articolo su rivista)
  • SCARSO A.; STRUKUL G Asymmetric sulfoxidation of aryl methyl sulfides with hydrogen peroxide in water in ROBERTS S.M.; WHITTALL; J., Catalysts for fine chemical synthesis: Regio- and stereo-controlled oxidation and reductions, CHICHESTER, John Wiley & Sons, vol. 5, pp. 297-302 (ISBN 9780470090220) (Articolo su libro)
  • FABRIS F; SCARSO A; TARTAGGIA S; BORSATO G; DE LUCCHI O.; LINDEN A Applicazioni Supramolecolari di Benzociclotrimeri in Società Chimica Italiana, XXXI Convegno Nazionale della Divisione di Chimica Organica, pp. MAT-O5, Convegno: XXXI Convegno Nazionale della Divisione di Chimica Organica, Cosenza (CS), 10-14 settembre (Articolo in Atti di convegno)
  • COLLADON M; SCARSO A.; STRUKUL G Catalytic Reactions in Micellar Media: a Sustainable Methodology for Catalyst Recycling, XIII ISHHC International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, Convegno: XIII ISHHC International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, Berkeley, CA, USA, July 16-20 (Articolo in Atti di convegno)
  • A. SCARSO; STRUKUL G. Catalytic Reactions in Micellar Media: a Sustainable Methodology for Catalyst Recycling, XV Congresso Nazionale di Catalisi GIC 2007, Convegno: XV Congresso Nazionale di Catalisi GIC 2007, Tirrenia (Articolo in Atti di convegno)
  • A. SCARSO; M. COLLADON; STRUKUL G. trans-Anethole Production Through Selective Catalytic Isomerization Reaction with Electron Poor Pt(II) Complexes, XV Congresso Nazionale di Catalisi GIC 2007, Tirrenia, Convegno: XV Congresso Nazionale di Catalisi GIC 2007, Tirrenia (Articolo in Atti di convegno)

2006

  • COLLADON M; SCARSO A.; SGARBOSSA P; MICHELIN R.A; STRUKUL G Asymmetric epoxidation of terminal alkenes with hydrogen peroxide catalyzed by pentafluorophenyl Pt(II) complexes, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 128, pp. 14006-14007 (ISSN 0002-7863) Link DOI (Articolo su rivista)
  • P. SGARBOSSA; E. PIZZO; A. SCARSO; MAZZEGA SBOVATA S.; R. A. MICHELIN; M. MOZZON; STRUKUL G.; F. BENETOLLO Bis-phosphine monoxide platinum(II) and palladium(II) cationic complexes as Lewis acid catalysts in Diels–Alder and sulfoxidation reactions, in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 691, pp. 3659-3666 (ISSN 0022-328X) (Articolo su rivista)
  • E. PIZZO; P. SGARBOSSA; A. SCARSO; R. A. MICHELIN; STRUKUL G. Second Generation of Electron Poor Pt(II) Complexes as Efficient Epoxidation Catalysts for Terminal Alkenes with Hydrogen Peroxide, in ORGANOMETALLICS, vol. 25, pp. 3056-3062 (ISSN 0276-7333) (Articolo su rivista)
  • COLLADON M; SCARSO A; STRUKUL G. Tailoring Pt(II) Chiral Catalyst Design for Asymmetric Baeyer-Villiger ­Oxidation of Cyclic Ketones with Hydrogen Peroxide, in SYNLETT, vol. 20, pp. 3515-3520 (ISSN 0936-5214) (Articolo su rivista)
  • SCARSO A.; REBEK. J.JR Chiral Spaces in Supramolecular Assemblies in REINHOUDT D.N.; CREGO-CALAMA M., Supramolecular Chirality , in TOPICS IN CURRENT CHEMISTRY, Stuttgart, Springer, vol. 265, pp. 1-46 (ISBN 9783540321514) (ISSN 0340-1022) (Articolo su libro)
  • SCARSO A.; COLLADON; M; SGARBOSSA P; MICHELIN R.A; STRUKUL G Asymmetric Epoxidation of Terminal Alkenes with Hydrogen Peroxide Catalyzed by Pentafluorophenyl PtII Complexes, 1st European Chemistry Congress, Convegno: 1st European Chemistry Congress, Budapest, Hungary, August 27-31 (Articolo in Atti di convegno)
  • A. SCARSO; M. COLLADON; P. SGARBOSSA; R. A. MICHELIN; STRUKUL G. Enantioselective Epoxidation of Simple Terminal Olefins with Hydrogen Peroxide Catalyzed by Pt (II) Complexes, 1st European Chemistry Congress, BUDAPEST, Convegno: 1st European Chemistry Congress, 26-31/08 (Articolo in Atti di convegno)

2005

  • SCARSO A.; STRUKUL G. Asymmetric Sulfoxidation of Thioethers with Hydrogen Peroxide in Water Mediated by Platinum Chiral Catalyst, in ADVANCED SYNTHESIS & CATALYSIS, vol. 347, pp. 1227-1234 (ISSN 1615-4150) (Articolo su rivista)
  • MICHELIN R. A; PIZZO E; SCARSO A.; SGARBOSSA P; STRUKUL G; TASSAN; A Baeyer-Villiger Oxidation of Ketones Catalyzed by Platinum(II) Lewis Acid Complexes Containing Coordinated Electron-poor Fluorinated Diphosphines, in ORGANOMETALLICS, vol. 24, pp. 1012-1017 (ISSN 0276-7333) (Articolo su rivista)
  • CONTE V.; FLORIS B.; GALLONI P.; MIRRUZZO V.; SCARSO A.; SORDI D.; STRUKUL G. The Pt(II)-catalyzed Baeyer–Villiger oxidation of cyclohexanone with H2O2 in ionic liquids, in GREEN CHEMISTRY, vol. 7, pp. 262-266 (ISSN 1463-9262) (Articolo su rivista)
  • A. SCARSO; P. SGARBOSSA; R. A. MICHELIN; STRUKUL G. Mild catalytic oxidation of tertiary amines to N-oxides withy H2O2 mediated by Pt(II) catalysts, XII International Symposium on the Relations between Heterogeneous and Homogeneous Catalysis, FIRENZE, Convegno: XII International Symposium on the Relations between Heterogeneous and Homogeneous Catalysis, 18-22/07 (Articolo in Atti di convegno)
  • R. A. MICHELIN; E. PIZZO; A. SCARSO; P. SGARBOSSA; STRUKUL G.; A. TASSAN Platinum(II) complexes with alkyldiphosphines as catalysts in the Baeyer-Villiger oxidation of cyclic ketones, XIV Congresso Nazionale di Catalisi, VERBANIA, Convegno: XIV Congresso Nazionale di Catalisi, 20-24/06 (Articolo in Atti di convegno)

2004

  • ZHAO Y.-L; HOUK K. N; RECHAVI D; SCARSO A.; REBEK J,JR Equilibrium Isotope Effects as a Probe of Nonbonding Attractions, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, pp. 11428-11429 (ISSN 0002-7863) (Articolo su rivista)
  • SCARSO A.; TREMBLEAU L; REBEK J; JR Helical Folding of Alkanes in a Self-Assembled, Cylindrical Capsule, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, pp. 13512-13518 (ISSN 0002-7863) Link DOI (Articolo su rivista)
  • RECHAVI D; SCARSO A.; REBEK J; JR Isotopomer Encapsulation in a Cylindrical Molecular Capsule: A Probe for Understanding Noncovalent Isotope Effects on a Molecular Level, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, pp. 7738-7739 (ISSN 0002-7863) (Articolo su rivista)
  • SCARSO A.; ONAGI H.; REBEK J.JR. Mechanically Regulated Rotation of a Guest in a Nanoscale Host, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, pp. 12728-12729 (ISSN 0002-7863) (Articolo su rivista)
  • SCARSO A.; REBEK J; JR Single Molecule Solvation and Its Effects on Tautomeric Equilibria in a Self-Assembled Capsule, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, pp. 8956-8960 (ISSN 0002-7863) (Articolo su rivista)
  • SCARSO A., Shivanyuk A., Hayashida O., Rebek J. Jr. Chiral Spaces in Encapsulation Complexes in PALYI G.; ZUCCHI C.; CAGLIOTI L., Progress in Biological Chirality, Oxford, Elsevier, pp. 261-270 (ISBN 9780080443966) (Articolo su libro)
  • SCARSO A., Scrimin P. DNA-cleaving pseudopeptides in P. E. NIELSEN, Pseudo-peptides in Drug Discovery, Weinheim, Wiley-VCH, pp. 223-240 (ISBN 9783527306336) (Articolo su libro)
  • RECHAVI D; SCARSO A.; REBEK J. JR Isotope Effects on Non-Covalent Host-Guest Interactions in a Cylindrical Molecular Capsule, 227th ACS National Meeting, Convegno: 227th ACS National Meeting, Anaheim, CA, United States, March 28 April 1 (Articolo in Atti di convegno)
  • SCARSO A.; STRUKUL G New Asymmetric Sulfoxidation of Thioethers Mediated by Pt Chiral Catalyst With H2O2 in Micellar Media, XIV International Symposium on Homogeneous Catalysis ISHC-14, Convegno: XIV International Symposium on Homogeneous Catalysis ISHC-14, Munich, GERMANY, JULY, 5-9 (Articolo in Atti di convegno)

2003

  • SCARSO A.; SHIVANYUK A; HAYASHIDA O; REBEK J.JR Asymmetric Environments in Encapsulation Complexes, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 125, pp. 6239-6243 (ISSN 0002-7863) (Articolo su rivista)
  • SHIVANYUK A; SCARSO A.; REBEK J.JR Coencapsulation of Large and Small Hydrocarbons, in CHEMICAL COMMUNICATIONS, pp. 1230-1231 (ISSN 1359-7345) (Articolo su rivista)
  • SCARSO A.; TREMBLEAU L; REBEK J. JR Encapsulation Induces Helical Folding of Alkanes, in ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, vol. 42, pp. 5499-5502 (ISSN 1433-7851) (Articolo su rivista)
  • SCARSO A.; SHIVANYUK A; REBEK J. JR Individual Solvent/Solute Interactions through Social Isomerism, in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 125, pp. 13981-13983 (ISSN 0002-7863) (Articolo su rivista)
  • SCARSO A.; SHIVANYUK A; HAYASHIDA O; REBEK. J.JR Guest Induced Chirality in a Self-assembled Capsule, 225th American Chemical Society National Meeting, Convegno: 225th American Chemical Society National Meeting, New Orleans, Luisiana, USA, March, 23-27, 2003 (Articolo in Atti di convegno)

2002

  • SCARSO A.; SCHEFFER U; GOEBEL M; BROXTERMAN Q.B; KAPTEIN B; FORMAGGIO F; TONIOLO C; SCRIMIN P A Peptide Template as an Allosteric Supramolecular Catalyst for the Cleavage of Phosphate Esters, in PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, vol. 99, pp. 5144-5149 (ISSN 1091-6490) (Articolo su rivista)

2001

  • G. LICINI; M. GOBBO; SCARSO A.; P. SCRIMIN; S. VALENTE Allosteric Regulation of a HIV-1 Protease Inhibitor by Zn(II) Ions, in ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, vol. 20, pp. 3899-3902 (ISSN 1433-7851) (Articolo su rivista)
  • SCARSO A.; SCRIMIN P Allosteric regulation of a tripodal peptidic templates as models of phosphoesterase, COST D11 Annual Meeting “Fourth COST D 11 Workshop on Supramolecular Chemistry”, Convegno: COST D11 Annual Meeting “Fourth COST D 11 Workshop on Supramolecular Chemistry”, Bled (Slovenia),, September 20-23 (Articolo in Atti di convegno)

2000

  • SCARSO A.; SCRIMIN P Synthesis of tripodal peptidic templates, EURESCO CONFERENCE ON SUPRAMOLECULAR CHEMISTRY, Convegno: EURESCO CONFERENCE ON SUPRAMOLECULAR CHEMISTRY, URBINO, ITALY, AUGUST, 31ST-SEPTEMBER 5TH (Articolo in Atti di convegno)

Curriculum di Alessandro SCARSO

Alessandro Scarso, PhD

Personal Information

Permanent address: Universitá Cá Foscari di Venezia,

Calle Larga Santa Marta 2137,

30123, VENICE, ITALY

Phone: +39 041-2348569, lab. +39041-2348575

Fax: +39041-2348517

e-mail: alesca@unive.it

Education and Work Experience

July 1991 SecondarySchool Graduation "Industrial Chemist" at I.T.I.S. "G. Natta" of Padova. Marks:60/60.

November 1998 Degree in Chemistry(5 years) at the Universitá di Padova (Organic Chemistry Department) with athesis dealing with catalytic asymmetric reactions "Complexes of Ti(IV) andZr(IV) with chiral trialkanolamine ligands with C3-symmetry inAsymmetric Catalysis" Marks: 110/110 with honours.

Supervisor: Prof.Giulia M. Licini

Activity:

Synthesis of chiral complexes of Ti(IV) and Zr(IV) and solutionspeciation of the complexes by means of 2D-NMR, molecular weight determinationin solution. Catalytic activity of such complexes as chiral Lewis acids in theasymmetric oxidation of sulfides to sulfoxides and Asymmetric Diels-Alderreactions.

May 1999 Habilitationto the Chemist Profession. Marks: 120/130.

Nov. 1998-Nov. 2001 PhD thesisin Chemical Sciences at Università degli Studi di Padova, Organic Chemistry Department."Peptide models of phosphoesterases: synthesis, activity and allostericregulation of a tripodal template".

Supervisor: Prof. Paolo M. Scrimin

Activity:

Developmentof artificial phosphoesterase complexes as enzyme mimetics and allostericregulation of their activity. Synthesis and solutioncharacterization of the coordination ability of peptide-based tripodalcomplexes of Zn(II) and Cu(II). Catalytic activity in the hydrolysis ofphosphodiester model substrates and investigation of allosteric regulation bymetal coordination.

February 2002 DoctorateDegree at the Università degli Studi di Padova.

December 2001- May 2002 Winner of a competitive publicexamination for the assignment of a temporary contract (6 months) dealing with "SupramolecularSystems based on Peptidic Foldamers" at the Università degli Studi di Padova, OrganicChemistry Department.

Supervisor: Prof. Paolo M. Scrimin.

Activity:

Developmentof analytical methods for oligoribonucleotides analysis and catalytic activityof peptidic metal containing catalysts as phosphodiesterase artificial mimeticenzymes.

June 2002 Winner of aPost-Doctorate Fellowship at the Università degli Studi di Padova (2 years) forstudies on supramolecular chemistry. Marks: 85/100.

Supervisor:Prof. Paolo M. Scrimin.

Activity:

Developmentof self-assembling structures as new environments for catalytic reactions.

August2002-November 2003 PostDoctoral position "Skaggs Fellowship" at the Skaggs Institute for ChemicalBiology, The Scripps Research Institute, San Diego California.

Supervisor:Prof. Julius Rebek Jr.

Activity:

Synthesis and development of self-assembly nanosized molecular capsules.Investigation of the unique properties of the inner space of such molecularcontainers by means of 1D and 2D NMR techniques. In depth study ofcoencapsulation of different guests, asymmetric recognition, gas encapsulation,social isomerism, isotopic binding effect, conformation changes uponencapsulation, reactions within nanosized containers.

December 2003-April 2004 Winnerof a Fellowship (6 months) from I.N.S.T.M. (Consorzio Interuniversitario Nazionaleper la Scienzae Tecnologia dei Materiali) at the Università Ca' Foscari di Venezia, ChemistryDepartment.

Supervisor: Prof. Giorgio Strukul.

Activity:

Development of new processes for hydrogen peroxide activation for finechemical production

May 2004-October2005 Winnerof a two year Fellowship "Assegno di Ricerca" from Università Ca' Foscari diVenezia (Chemistry Department) dealing with "Reactivity of Recyclable Pt(II)and Pd(II) Catalysts in Selective Oxidation Reactions with Hydrogen Peroxide".

Supervisor:Prof. Giorgio Strukul.

Activity:

Development of new chiral and achiral complexes of Pt(II) and Pd(II) forhydrogen peroxide activation. Fine chemical production with new eco-friendly oxidationprocesses. Effect of the diphosphine ligand, Lewis acidity of the complexes oncatalytic activity.

Since November2005 AssistantProfessor position in Industrial Chemistry (CHIM/04) at the faculty ofScience of Universitá Ca' Foscari diVenezia, Chemistry Department.

Main Activity:

Developmentof new oxidation processes, hydrogen peroxide activation, asymmetric oxidationswith homogeneous and heterogeneous catalysts. Employment of new reaction medialike water in catalysis. Green chemistry. Supramolecular chemistry andcatalysis.

Current Teaching

Compulsory Courses:

IndustrialOrganic Chemistry

LabCourse 2nd year Master Degree in Industrial Chemistry. Since 2006.

New Frontiers in Catalysis 2nd year Master Degree inIndustrial Chemistry. Starting 2009-2010.

Optional Courses:

Supramolecular Chemistry

PhD course 12h

Supramolecular Catalysis

PhD course 12h

© Ca'Foscari 2014